Regulating Nonclassical Pathways of Silicalite‐1 Crystallization through Controlled Evolution of Amorphous Precursors

Mesocrystals and Nonclassical Crystallization

Mesocrystals and Nonclassical Crystallization

This chapter presents a history of observations that crystallization can go well beyond the simple ‘expected’ behaviour found in the salt cellar or when you buy a chemical. Biomorphs, crystal gardens, ‘crystal souls’, but also the remarkable pattern and structures of biominerals made researchers think that there is something beyond the concept of the bare three-dimensional regularity of molecul...

Non-isothermal Primary Crystallization Kinetics of the Amorphous Fe85.3B11P3Cu0.7 Alloy

In the present research, the primary crystallization kinetics of the amorphous Fe85.3B11P3Cu0.7 alloy was analyzed using non-isothermal DSC measurements. The average and local activation energies, Ea, were determined by different isokinetic and isoconversional methods. The results obtained for activation energy in this research, show that due to the complexity of the primary crystallization pro...

Simultaneous crystalline-amorphous phase evolution during crystallization of polymer systems

– Despite the fact that polymer crystallization has been the object of intense research, this process is far from being fully understood. Traditional polymer crystallization studies using X-ray scattering techniques mainly provide information about the ordered regions. To obtain a more complete information about the time evolution of both the crystalline and the amorphous phase during polymer c...

Crystallization Kinetics Study in Al87Ni10La3 Amorphous Alloy

In this study, the crystallization behavior of melt-spun Al87Ni10La3 amorphous phase was investigated by using X-ray diffraction and non-isothermal differential thermal analysis techniques. The results demonstrated that the amorphous phase exhibited two-stage crystallization on heating, i.e., at first step the amorphous phase transforms into α-Al phase and at second step Al11La3 and Al3Ni inter...